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Organometallics (1)

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Published on Apr 17, 2009

Organic chemistry: Halogenation of alcohols (PBr3, SOCl2). Organometallics (Grignards, alkyl lithiums, organocuprates). Using the retrosynthesis technique to solve synthesis problems involving organocuprates.

Some courses may not cover organocuprates. Check with your instructor.

This is a recording of a tutoring session, posted with the students' permission.

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(1) The SN2/SN1/E2/E1 handout. Halogenation of alcohols (SOCl2, PBr3)
(2) Continued. Organometallics. How to synthesize Grignards and alkyl lithiums
(3) Continued. Reactions of Grignards and alkyl lithiums
(4) Continued. Organocuprates
(5) Continued
(6) Using the "retrosynthesis" technique to solve a synthesis problem involving organocuprates
(7) Continued. The effect of size on nucleophilicity
(8) SN1 vs. E1. E2 stereochemistry


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