 This review covers all of the common methods for the synthesis of aromatic and heterocyclic perfluorocal sulfides, a class of compounds which is finding increasing application as starting materials for the preparation of agrochemicals, pharmaceutical products, and, more generally, fine chemicals. A systematic approach is taken depending on the mode of incorporation of the SRF groups, and also on the type of reagents used. This article was authored by Vladimir Enboyko.