 The study examined the effect of fractional distillation on the production of biofuels from a vicaric column under atmospheric pressure. Three distilled fractions were produced, green gasoline, green aviation kerosene, and green diesel. The results indicated that the distilled fractions met the standards set by national and international regulations for physical chemical properties and had similar distillation curves to those of conventional fuels. Furthermore, the fractions contained high levels of hydrocarbon components and low levels of oxygenated components, which are typical of petroleum derivatives. This article was authored by Silvio Alex P. Motasilvio, Andrea A. M. Mota-Andrea and Nelio T. Machado-Nelio.