 The development of new materials for the design of sensitive and responsive sensors has become a crucial research direction. Two silver cluster-based polymers, AGCBPS, 1-dimensional, AG22, L1, 8, CF3CO2, 14, CH3OH, 2-chain and 2-dimensional, AG12, L2, 2, CO2CF3, 14, H2O, 4, AGCO2CF3, 2-film, have been developed and used to simulate the human nose, an elegant sensor to smell, to distinguish organic solvents. The atomic structure of these materials was studied using X-ray diffraction, and the electrical properties were measured in the presence of organic solvents, methanol and ethanol. It was found that the ligands, cations, and ligated solvent molecules play an important role in the self-assembly process of AGCBP materials and determine their physical chemical properties such as the sensing functionality. This article was authored by Xiaoxian Qin, Jiwen Li, Satchel Sharma, and others. We are article.tv, links in the description below.