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Published on Apr 17, 2014
Table of Contents: 00:09 Week 2 Summary 00:23 Basic Thermodynamic Formulation (continued) 02:06 The Electrode Potential 03:16 Electrochemical Driving Forces 03:48 Building a Phase Diagram 04:39 Phase Diagrams and Material Potential 06:43 The LiFePO4 System 08:26 The Bi-Li System 09:37 Thermal Effects 11:35 Li-Sb-Bi System
This course will provide an introduction to the fundamentals behind the equilibrium and time-dependent response of existing and emerging chemistries of Li-ion battery materials. Effects of material selection and processing on the performance and reliability are presented as a means to develop conceptual guidelines to understand and improve battery designs. Example applications such as intercalation, SEI, and dendrite growth are presented. Integration of experimental microstructural aspects to coarse-graining measured properties, such as porosity, tortuosity and its associated reactivity, and classic and emerging battery architectures are presented. Principles summarizing the response of battery architectures are formulated and applied to propose battery design guidelines, to review existing porous electrode theory descriptions, and to summarize the current state-of-the-art of battery technology and its associated metrology.