 A photothermal isophobic MOF-based micro and nanostructure surface, MOF-MNS, is presented that consists of micron-groove structure and fluorinated MOF nanowiskers, which can achieve solar absorption of over 98% and produce a high temperature increment of 65.5 degrees Celsius under one sun illumination. The MOF-M250NS also generates an ultra-long icing delay time of approximately 3960 seconds at minus 18 degrees Celsius without solar illumination, achieving the longest delay time reported before. Due to its excellent solar-to-heat conversion ability, the accumulated ice and frost on MOF-M250NS can be rapidly melted within 720 seconds under one sun illumination and it also holds a high de-icing rate of 5.8 kilograms m-karat-2h-karat-1. The MOF-M250NS possesses the versatility of mechanical robustness, chemical stability, and low temperature self-cleaning, which can synergistically reinforce the usage of isophobic surfaces in harsh conditions. This article was authored by Lei Zhang, Binkai Luo, Ku'en Fu, and others. We are article.tv. Links in the description below.