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Who would want to whip it out and pee when it's -40, though? Something tells me that instantly frozen urine would suddenly not be that interesting when your man stick starts to freeze.
The reason boiling water freezes and urine doesn't is because of the starting temperature. Boiling water has sufficient energy to fuel the phase change from liquid to solid. Also, when you whip the water into the air it adds the factor of surface area of water exposed to air, which helps release the heat energy faster.
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