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Uploaded by on Jun 7, 2009

Crack cocaine, often nicknamed "crack" after the sound made during its manufacture, appeared primarily in impoverished inner-city neighborhoods in New York, Los Angeles, and Miami in late 1984 and 1985.[4] Because of the dangers for manufacturers of using ether to produce pure freebase cocaine, producers began to omit the step of removing the freebase precipitate from the ammonia mixture. Typically, filtration processes are also omitted. The end result is that the cut, in addition to the ammonium salt (NH4Cl), remains in the freebase cocaine after the mixture has evaporated. The "rock" that is thus formed also contains a small amount of water.


A spoon with a mixture of baking soda, cocaine and a small amount of water. When heated from below, small crack cocaine rocks will begin to form in the mixture.Baking soda is now most often used as a base rather than ammonia for reasons of lowered odor and toxicity; however, any weak base can be used to make crack cocaine. When commonly "cooked" the ratio is 3:4 parts cocaine per bicarbonate. This acts as a filler which extends the overall profitability of illicit sales. Crack cocaine may be reprocessed in small quantities with water (users refer to the resultant product as "cookback"). This removes the residual bicarbonate, and any adulterants or cuts that have been used in the previous handling of the cocaine and leaves a relatively pure, anhydrous cocaine base. The net reaction when using sodium bicarbonate (NaHCO3, common baking soda) is:

Coc-H+Cl + NaHCO3 → Coc + H2O + CO2 + NaCl

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