It is suggested that the current formalism describing the first law of thermodynamics is incorrect in solid phase. In this first part the universality of the Joules postulation regarding to the mechanical equivalency of heat is questioned.
You can find the proposed thermodynamic description of solids given in a more rigorous way by following macroscopic approach at:
http://www.garai-research.com/research%20statement/thermodynamics%20of%20soli...
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