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Chemistry: Transition metals and isomerism (1)

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Uploaded by on Jun 14, 2010

Chemistry: Transition metals and isomerism. Transition metal electron configurations for neutral atoms and cations. Coordination compounds; oxidation number and coordination number. Coordination isomers; linkage isomers. Structural isomers vs. stereoisomers. Geometric isomers. Optical isomers

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(1) Transition metal electron configurations for neutral atoms and cations
(2) Continued
(3) Continued
(4) Coordination compounds
(5) Oxidation number and coordination number
(6) Isomerism. Coordination isomers; linkage isomers. Structural isomers vs. stereoisomers
(7) Geometric isomers
(8) Continued
(9) Optical isomers
(10) Continued
(11) Continued
(12) Continued
(13) Continued

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  • Good lecture!

  • The configuration of Cr as [Ar] 4s1 3d5 is more stable than as [Ar] 4s2 3d4 due to its "more spherical" allocation near the nucleus. It's a rule for more stable configuration: "Configuration with half-completed p and d orbitals" and its the 3rd steadier configuration, after the "noble gas" and "completed p and d orbitals" configuration. (Sorry for my poor english :P)

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