Chemical Properties Of Metals

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Uploaded by on May 5, 2010

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A metal is a chemical element that is a good conductor of both electricity and heat and forms cations and ionic bonds with non-metals. In chemistry, a metal ( from Greek "μέταλλον" - métallon, "mine") is an element, compound, or alloy characterized by high electrical conductivity. In a metal, atoms readily lose electrons to form positive ions (cations). Those ions are surrounded by delocalized electrons, which are responsible for the conductivity. The solid thus produced is held by electrostatic interactions between the ions and the electron cloud, which are called metallic bonds.
Chemical properties of metals
Metals are usually inclined to form cations through electron loss,reacting with oxygen in the air to form oxides over changing timescales (iron rusts over years, while potassium burns in seconds). Examples:
4 Na + O2 → 2 Na2O (sodium oxide)
2 Ca + O2 → 2 CaO (calcium oxide)
4 Al + 3 O2 → 2 Al2O3 (aluminium oxide)
The transition metals (such as iron, copper, zinc, and nickel) take much longer to oxidize. Others, like palladium, platinum and gold, do not react with the atmosphere at all. Some metals form a barrier layer of oxide on their surface which cannot be penetrated by further oxygen molecules and thus retain their shiny appearance and good conductivity for many decades (like aluminium, some steels, and titanium). The oxides of metals are generally basic, as opposed to those of nonmetals, which are acidic.
Painting, anodizing or plating metals are good ways to prevent their corrosion. However, a more reactive metal in the electrochemical series must be chosen for coating, especially when chipping of the coating is expected. Water and the two metals form an electrochemical cell, and if the coating is less reactive than the coatee, the coating actually promotes corrosion.

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