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Quantum Mechanics: The Structure Of Atoms

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Uploaded on Jan 2, 2010

http://www.facebook.com/ScienceReason ... Quantum Mechanics (Chapter 2): The Structure Of Atoms.

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1. A Brief History Of Quantum Mechanics
http://www.youtube.com/watch?v=B7pACq...
2. The Structure Of Atoms
http://www.youtube.com/watch?v=-YYBCN...
3. Wave Function And Wave-Particle Duality
http://www.youtube.com/watch?v=7GTCus...
4. The Uncertainty Principle
http://www.youtube.com/watch?v=Fw6dI7...
5. The Spin Of Fundamental Particles
6. Quantum Entanglement

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Atomic Structure

It was during the early decades of the 19th century that the structure of atoms was coming into focus. It was known for example that a hydrogen atom contained one proton and one electron. But the scientists of the time could think of no stable arrangement of the two particles.

It was known that protons in any atom were grouped in a small central region called the nucleus and that the electrons were somehow arranged at comparatively large distances outside the nucleus. But, in hydrogen, if the electron were stationary, it would fall into the nucleus since the charges on the particles would cause them to attract one another.

Yet the electron couldnt be in an orbit circling the nucleus either. Circular motion requires constant acceleration of the circling body to keep it from flying away. But the electron has charge and charged particles radiate light when they are accelerating. So an electron in a circular orbit would radiate light and would spiral into the nucleus.

Bohr Atom

Niels Bohr proposed the first working model of the hydrogen atom. In the Bohr model, the electron circles the nucleus as if it were a planet going around the sun. And with a nod to the energy quantization that Max Planck dreamed up for solving the Ultraviolet Catastrophe, Bohr said that inside the hydrogen atom, the electron was allowed to have only discrete values of angular momentum in its orbits around the nucleus.

Translated, this means the electron can occupy orbits only at a certain distances from the nucleus. And Bohr simply dismissed the problem of the electron radiating away its energy by stating that it just didnt happen (even great scientists cheat sometimes!). He postulated that inside an atom, electrons only radiate energy when they jump from one allowable orbit to another, and the energy of this radiation, reveals the allowable orbits.

The wavelengths of light absorbed by hydrogen when white light is shined upon it, as well as the wavelengths of light when it is subsequently re-radiated had been precisely studied at the time but never explained. Here is a sample of an absorption spectrum and an emission spectrum.

By predicting the values of orbits that an electron could have, Bohrs model also predicted the wavelengths of the lines in the hydrogen spectrum. And his model was tremendously successful. It explained in exquisite detail the atomic spectra of hydrogen.

When the energy of the wavelengths of the spectral lines are compared to the energy differences in orbits allowed in the Bohr Atom they agree exactly. So the quantum approach worked well in explaining the allowable orbits, but no one was certain why only those orbits were allowed.

Particle Waves

In his doctoral dissertation in 1924, Louis de Broglie put forward a simple idea that significantly advanced the understanding of the extremely tiny (a quantum leap forward you might say). Since Einstein and Planck and Compton had firmly established that light could have characteristics of both a wave and a particle, de Broglie suggested that matter particlesprotons, electrons, atoms, billiard balls, etc. could sometimes act like waves.

And when this idea was applied to the Bohr atom, it answered many questions. First, the allowed orbits had to be exact multiples of the wavelengths calculated for the electrons. Other orbits produced destructive interference of the waves and so the electron couldnt exist there.

So the circumference of the orbit must equal the wavelength Or twice the wavelength Or 3 times the wavelength Or, for that matter, any multiple of the wavelength. Second, these orbits werent really orbits in the traditional sense. These electrons didnt travel around the nucleus in a circle. Rather they took the form of a standing wave that surrounded the nucleus entirely. The exact position and momentum of the electron particle could not be specified at any given instant.

http://www.cassiopeiaproject.com
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Top Comments

  • 6missiles

    the person at 00:05 scared the fuck out of me

    · 184

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  • kittysaurusrecks

    I have never been more confused in my life

    · 31

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Video Responses

This video is a response to A Brief History Of Quantum Mechanics

All Comments (422)

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  • Seamless Robe

    Wave front onions coming into and out of existence seem to contain much the same information as before.

    This is rather like looking at waves coming to a sea shore!

    A wave comes and breaks, then it withdraws, and other wave comes which may contain much of the same water as before, and another wave comes. . .there is no permanent central water within these succeeding waves as time unfolds, and depending which neurons gets stimulated, certain connections become stronger whilst others become weaker.

    ·

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  • Mark Denman

    what's funny?

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    in reply to mkhanhassan (Show the comment)
  • Mark Denman

    The video is 6 minutes and 11 seconds.

    If you want to understand quantum mechanics more thoroughly I would suggest doing more than clicking on short videos on youtube

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  • T2Exile

    PINK FLOYD

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  • lukealization

    Wow! 9 months later and someone delivers! Excellent detective work, AlphaCrucis! You're awesome.

    ·

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    in reply to AlphaCrucis (Show the comment)
  • AlphaCrucis

    After years of searching, I found the music on "FirstCom Music". It seems that most of the music used in these videos is by Aaron Wheeler. There are two albums on there called Futurism and Futurescapes that contain much of the music used in Quantum Mechanics and the Standard Model of Particle Physics. There are still a few songs that I haven't found yet though.

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    in reply to lukealization (Show the comment)
  • mkhanhassan

    LOL. You need to have a background understanding of atomic structure.

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    in reply to kittysaurusrecks (Show the comment)
  • Nashun66

    this too complicated

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  • Nashun66

    This this complicated

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