con....last time I promise...to sulfunize benzene you gotta heat the benzene in flask with an upright condenser. The heated benzene has a little con. H2SO4 in it and as it heats (a long time.... :( it will not evaporate as it cools and goes back down to the flask. Hense; reflux heating for long periods without loosing slovent. (heat about 4 to 6 hours)
....try sticking to formula, I guess? Maybe you can use potassium hydroxide Looking up this stuff a SAFE way may take days. Tiny mistake use a LARGE PAINT CAN as you dump your your molten sodium hydroxide to the sufinized benzene. Again; a LARGE PAINT CAN with your relatively small amount of sufinized benzene. It's is gonna splatter. Do outside. Ware thick gloves and thick arm and protection for your face. P.T. Alpha and Omega for Phenol plastics....etc....Box Club rules.... too.
Please please please forgive me for being verbose. I forgot to say after you put the molten sodium hydroxide to the SULFINIZED BENZENE, (and it WILL SPATTER BADLY -wear thick gloves and arm protection-but you get LOTS OF PHENOL), do an acid work up, by very dilute sulfuric acid into latter via crunching up your "rocks" from the molten job... crystalize in cold place with fan on it, if no crystals- add more H2SO4. in luie of the latter BOX CLUB RULES , 44mph on car, say greeting, ETC... call me.
Makeing phenol is one of the highest accomplishments one could ever achieve in the 21st century!!!!!! PTL Highest Spirit/
(I speak in luie of part time work only, 40 no more speed, publish eerywhere, say the latter as greeting fpr love of others, eternal life, Future Consciousness Unit for unravelling disapping stuff, contact me for Spiritual abilities, and no fears of things or people, write things down. Sounds bad for a person to say this but it is necessary. I have done this for 10+ years).
...cont.... I speak in addition to priseing the Alpha and Omega Spirit Point, THE BOX CLUB rules, 44mph max sticker on vehicles, 25 hours work no more, say the latter at all stores as "greeting," I think Im the guy you wanna meet with and publish the "Greeting" on and off media. It is a Large Quantum World. AGain, THANK YOU FOR YOUR contacting me about the latter only. :O) Oh yes, LOVE comes from appreciating everything like this guys Phenol way as well as mine
Phenol VIA Benzene 1. Benzene to "Sufo.-benzene-" do HEAT benzene first THEN add some con H2SO4. But not too much H2SO4 It will REVERSE "sulfonizing" 2."Sulfo-benzene" to sodium pheoxide | Do this in tiny paint can of molten SOD. HYDROX added to tiny paint can of sulfoben. BUT LOOK OUT! It is GONNA SPATTER-YET WORKS :o) 3. sod-.phenox. acidfication is done via a LITTLE dilute sulferic acid to Sodphenox. and stir The thick stuff SOULD crystalize Phenol P! I say all this in luie of ...cont...
Oh...let me add....THE PERSECUTION is typical for being so loving for this fine video. hehehe...."IT'S ALL FOR THE BEST!"-Godspell ptl....AND THE PRIMER things, of course.
Praise God Almighty (A.K.A. Higher Power, Greatest Spirit) for this video. IT IS SAFE AS WELL AS EASY to follow and do for the appreciation MOVEMENT. NOW let us see if we REALLY need those guys at the store! "He who appreciates the most the longest- wins!"-John T. Schiffer Jr
(I only say this in liue of part time, no hard quota jobs only, 44mph max sticker on cars, publish this stuff on trash cans too, say such things at stores for the movements, witness for your government, for 30 years.)
@havabighed You clearly have an elementary grade chemistry knowledge that you should expand. All kinds of things can be considered as acids as there are several theories what an acid is.
@endimion17 I didnt say his videos are stupid... I said "this is stupid" meaning, that he could have gotten the same results(phenol/benzenol) with a much much simpler process.
But also, in his videos he never mentions the molarities of solutions.... "100mg of this and 100mg of that", he needs to say the molarity of each solution.
I've seen what both of these chemicals can do. Aniline will remove the oxygen out of your blood. Even a small drop on your body can kill you. Phenol smells like soar throat medicine and damage your nerve system.
I've never been exposted to Aniline, though I did have a friend nearly die from a drop that spilled on his boots and soaked through to his skin. I did have a rather nasty experience with Phenol under a pressurized tank.
Amazing this chemical is a byproduct of refining crude oil.
@thegreatwoodlife Aniline?? are you sure your not confusing this with something else. It's DERMAL (LD50) is 1400 mg/kg [Rat]. Granted I would not want it on me. We used Aniline in our organic chem lab at college years ago... I am pretty sure they would not let students handle something that would kill you if a drop got on you. The MSDS states "Slightly hazardous in case of skin contact ". Dimethylmercury will kill you if a drop gets on you and it will soak through rubber gloves.
@myst32YT Not sure what grade you're using, but I'm refering aniline that's strait from the chemical plant. I'm pretty sure that the civilian population is not capable of even aquiring it at this stage, so that's possible. If you think about it this way, I delt with chemicals in their raw form. You can take 100% Acetic Acid, and make 100% veniger with just 10% of the Acetic Acid. So then it goes from very harmful, to a commercial grade food additive. That's likely the reason for the difference.
@thegreatwoodlife Aniline attaches itself on your red blood cells making oxygen absorption impossible a human body can't brake down aniline.
A large drop Phenol will kill you. Its melting point is 40° a bit above the human body temperature in contact with skin it gives white burns with red around the contamination zone. It disables the kidney functions.
did you know that as a byproduct of a glow stick reaction, small amounts of phenol are made and im pretty sure it could also be extracted with enough glowsticks (round the 50 mark with small glow sticks or the any larger will work better)
if he would have acidified the KI solution before adding it into the ether would have dissolved the Iodine.
the point of not acidifying the KI is to test the Ether for any peroxide. The peroxide would oxide the iodide in the KI to Iodine. Then the Iodine will dissolve into the Ether and turn the solution purple/pink-ish
@chemicalsymphony Yes, you can make it from the diamine, which you can make from reduction of m-dinitrobenzene, which you can get from the two-step nitration of benzene. All in all, too much work, I just buy resorcinol.
Do you think that phenols can be made from anilines too trough HCl and nitrate (or nitric)? Just like one can make benzoquinone from paracetamol, but phenol not being prone tu such overoxidation... check out SM or versuschemie for more details.
Other ways, nice vid! I'd use salting out for a better extraction of the phenol and I would tri to purify it trough the sodium salts it forms.
@LazyPL You do decarboxylation of salicylic acid... basically just boil it with concentrated hydrochloric acid.... but I dont recommend taking advice from this guy, he doesnt seem to fully understand what hes doing.... for one, phenol is corrosive, but it isnt an acid.
many of the methods ive seen him use are overly complex and can be simplified with greater yields.
@endimion17 its more of an alcohol than an acid.... and atoms dont "donate protons", in fact... you cant chemically put a proton into another atom without using physics, say a proton collider..... And I have a university level understanding of Chemistry....
awesome video! Is there a safe way (explosion hazard?) to make phenol from salicylic acid? I've heard that phenol is formed when salicylic is heated to about 200C. Is this method safe and/or feasible? i doubt you'd get a pure product if any.
con....last time I promise...to sulfunize benzene you gotta heat the benzene in flask with an upright condenser. The heated benzene has a little con. H2SO4 in it and as it heats (a long time.... :( it will not evaporate as it cools and goes back down to the flask. Hense; reflux heating for long periods without loosing slovent. (heat about 4 to 6 hours)
shiftgood1 1 month ago
....try sticking to formula, I guess? Maybe you can use potassium hydroxide Looking up this stuff a SAFE way may take days. Tiny mistake use a LARGE PAINT CAN as you dump your your molten sodium hydroxide to the sufinized benzene. Again; a LARGE PAINT CAN with your relatively small amount of sufinized benzene. It's is gonna splatter. Do outside. Ware thick gloves and thick arm and protection for your face. P.T. Alpha and Omega for Phenol plastics....etc....Box Club rules.... too.
shiftgood1 1 month ago
Please please please forgive me for being verbose. I forgot to say after you put the molten sodium hydroxide to the SULFINIZED BENZENE, (and it WILL SPATTER BADLY -wear thick gloves and arm protection-but you get LOTS OF PHENOL), do an acid work up, by very dilute sulfuric acid into latter via crunching up your "rocks" from the molten job... crystalize in cold place with fan on it, if no crystals- add more H2SO4. in luie of the latter BOX CLUB RULES , 44mph on car, say greeting, ETC... call me.
shiftgood1 1 month ago
Can I use potassium nitrate, not sodium nitrate?
OMKBialystok 1 month ago
Do you own a professional ice machine?
98JMA 1 month ago
Makeing phenol is one of the highest accomplishments one could ever achieve in the 21st century!!!!!! PTL Highest Spirit/
(I speak in luie of part time work only, 40 no more speed, publish eerywhere, say the latter as greeting fpr love of others, eternal life, Future Consciousness Unit for unravelling disapping stuff, contact me for Spiritual abilities, and no fears of things or people, write things down. Sounds bad for a person to say this but it is necessary. I have done this for 10+ years).
shiftgood1 1 month ago
...cont.... I speak in addition to priseing the Alpha and Omega Spirit Point, THE BOX CLUB rules, 44mph max sticker on vehicles, 25 hours work no more, say the latter at all stores as "greeting," I think Im the guy you wanna meet with and publish the "Greeting" on and off media. It is a Large Quantum World. AGain, THANK YOU FOR YOUR contacting me about the latter only. :O) Oh yes, LOVE comes from appreciating everything like this guys Phenol way as well as mine
shiftgood1 1 month ago
Phenol VIA Benzene 1. Benzene to "Sufo.-benzene-" do HEAT benzene first THEN add some con H2SO4. But not too much H2SO4 It will REVERSE "sulfonizing" 2."Sulfo-benzene" to sodium pheoxide | Do this in tiny paint can of molten SOD. HYDROX added to tiny paint can of sulfoben. BUT LOOK OUT! It is GONNA SPATTER-YET WORKS :o) 3. sod-.phenox. acidfication is done via a LITTLE dilute sulferic acid to Sodphenox. and stir The thick stuff SOULD crystalize Phenol P! I say all this in luie of ...cont...
shiftgood1 1 month ago
you lost me after 2:00
LOL64431 1 month ago
Oh...let me add....THE PERSECUTION is typical for being so loving for this fine video. hehehe...."IT'S ALL FOR THE BEST!"-Godspell ptl....AND THE PRIMER things, of course.
shiftgood1 2 months ago
Praise God Almighty (A.K.A. Higher Power, Greatest Spirit) for this video. IT IS SAFE AS WELL AS EASY to follow and do for the appreciation MOVEMENT. NOW let us see if we REALLY need those guys at the store! "He who appreciates the most the longest- wins!"-John T. Schiffer Jr
(I only say this in liue of part time, no hard quota jobs only, 44mph max sticker on cars, publish this stuff on trash cans too, say such things at stores for the movements, witness for your government, for 30 years.)
shiftgood1 2 months ago
hence the phen-OL.... cause all alcohols end with "ol".... like methanol, and ethanol...... and phenOL.....
havabighed 2 months ago
wow, this is stupid....... phenol is not an acid, its an alcohol.
havabighed 2 months ago
@havabighed You clearly have an elementary grade chemistry knowledge that you should expand. All kinds of things can be considered as acids as there are several theories what an acid is.
His videos aren't stupid at all.
endimion17 2 months ago
@endimion17 I didnt say his videos are stupid... I said "this is stupid" meaning, that he could have gotten the same results(phenol/benzenol) with a much much simpler process.
But also, in his videos he never mentions the molarities of solutions.... "100mg of this and 100mg of that", he needs to say the molarity of each solution.
havabighed 2 months ago
@endimion17 The reason I say its more of an alcohol than an acid is because you can readily form esters with it.... like phenyl stearate.
havabighed 2 months ago
phenol....
myst32YT 2 months ago
@myst32YT - what's the side product if you heat up the diazonium too high? I would have thought more heat just result in a higher rate of reaction.
MrSmudger687 2 months ago
phenol...
myst32YT 2 months ago
are you saying phenol or phenyl?
candlertower 2 months ago
yay...i didnt understand any of this but it sounds good
kny1000pegasis 3 months ago
I see where you're going with this. Is the next step making phenylacetone in a tube furnace and then using reductive amination to yield...
opl500 3 months ago
I've seen what both of these chemicals can do. Aniline will remove the oxygen out of your blood. Even a small drop on your body can kill you. Phenol smells like soar throat medicine and damage your nerve system.
I've never been exposted to Aniline, though I did have a friend nearly die from a drop that spilled on his boots and soaked through to his skin. I did have a rather nasty experience with Phenol under a pressurized tank.
Amazing this chemical is a byproduct of refining crude oil.
thegreatwoodlife 6 months ago
@thegreatwoodlife Aniline?? are you sure your not confusing this with something else. It's DERMAL (LD50) is 1400 mg/kg [Rat]. Granted I would not want it on me. We used Aniline in our organic chem lab at college years ago... I am pretty sure they would not let students handle something that would kill you if a drop got on you. The MSDS states "Slightly hazardous in case of skin contact ". Dimethylmercury will kill you if a drop gets on you and it will soak through rubber gloves.
myst32YT 6 months ago
@myst32YT Not sure what grade you're using, but I'm refering aniline that's strait from the chemical plant. I'm pretty sure that the civilian population is not capable of even aquiring it at this stage, so that's possible. If you think about it this way, I delt with chemicals in their raw form. You can take 100% Acetic Acid, and make 100% veniger with just 10% of the Acetic Acid. So then it goes from very harmful, to a commercial grade food additive. That's likely the reason for the difference.
thegreatwoodlife 6 months ago
@myst32YT There's no way a drop of aniline applied topically will kill a kid, let alone an adult.
It is hazardous, but a drop won't do anything.
endimion17 2 months ago
@thegreatwoodlife phenol is also used in deep chemical peels, scar removal.
havabighed 2 months ago
@thegreatwoodlife Aniline attaches itself on your red blood cells making oxygen absorption impossible a human body can't brake down aniline.
A large drop Phenol will kill you. Its melting point is 40° a bit above the human body temperature in contact with skin it gives white burns with red around the contamination zone. It disables the kidney functions.
ElJozir 1 month ago
How to make phenol from benzene and Fenton's reagent?
yellowmetalcyborg 6 months ago
did you know that as a byproduct of a glow stick reaction, small amounts of phenol are made and im pretty sure it could also be extracted with enough glowsticks (round the 50 mark with small glow sticks or the any larger will work better)
toothpick93 6 months ago
Why didn´t you acidified your KI solution before you add the ether?
olympicfan2 8 months ago
@olympicfan2
if he would have acidified the KI solution before adding it into the ether would have dissolved the Iodine.
the point of not acidifying the KI is to test the Ether for any peroxide. The peroxide would oxide the iodide in the KI to Iodine. Then the Iodine will dissolve into the Ether and turn the solution purple/pink-ish
Aranwu 6 months ago
Can you make resorcinol (1,3-dihydroxybenzene) using this or a similar method?
chemicalsymphony 8 months ago
@chemicalsymphony Yes, you can make it from the diamine, which you can make from reduction of m-dinitrobenzene, which you can get from the two-step nitration of benzene. All in all, too much work, I just buy resorcinol.
LHCb42 8 months ago
Do you think that phenols can be made from anilines too trough HCl and nitrate (or nitric)? Just like one can make benzoquinone from paracetamol, but phenol not being prone tu such overoxidation... check out SM or versuschemie for more details.
Other ways, nice vid! I'd use salting out for a better extraction of the phenol and I would tri to purify it trough the sodium salts it forms.
Have a nice day.
Palizasadomicilio 8 months ago
becarfull i herd phenol is a carsinagin and a explosive but thats what i herd im not shur if it is true or not though
AlChemicalLife 8 months ago
Nice Video
zzanzak 9 months ago
Do you think that making phenol from salicylic acid (can be made from aspirin) may be akin to making benzene from benzoic acid?
ChemCrazy81 9 months ago
I think that salicylic acid can be oxidised under certain conditions to give CO2 and Ph-OH. I am not entirely sure thought.
deathnoteviewer 9 months ago
@h0meIandsecurity Ohh...it's a diazonium salt...
myst32YT 9 months ago
@h0meIandsecurity look up the Sandmeyer reaction...
myst32YT 9 months ago
great video
coolliger 9 months ago
How to make phenol from salicylic acid?
LazyPL 9 months ago 13
@LazyPL Acetylsalicylic acid too! Cheap
ChemCrazy81 9 months ago
@LazyPL Will look into it...
myst32YT 9 months ago
@LazyPL Ok, this works.... just not very well.... I will put the video on it later...
myst32YT 9 months ago 7
@myst32YT Thank you :)
LazyPL 9 months ago
@myst32YT I am looking forward to that video! :)
Chrelle4ever 6 months ago
@LazyPL You do decarboxylation of salicylic acid... basically just boil it with concentrated hydrochloric acid.... but I dont recommend taking advice from this guy, he doesnt seem to fully understand what hes doing.... for one, phenol is corrosive, but it isnt an acid.
many of the methods ive seen him use are overly complex and can be simplified with greater yields.
havabighed 2 months ago
@havabighed Are you sure it can't behave like an acid? AFAIK, it donates its proton quite well. It's considered to be a weak acid.
endimion17 2 months ago
@endimion17 its more of an alcohol than an acid.... and atoms dont "donate protons", in fact... you cant chemically put a proton into another atom without using physics, say a proton collider..... And I have a university level understanding of Chemistry....
havabighed 2 months ago
@LazyPL no... the real question is how to make phenol from asprin... and the answer is in my brain. ;-)
havabighed 2 months ago
Great video! I like your steam distillation setup. I will have to try that for extracting essential oils.
purplemutantas 9 months ago
Well done once again !!!! Great synthesis and video, looking forward to the next one, thanks
aaronjhard 9 months ago
Nice synthesis and a nice pure product. Well done!
DoktorKlawonn 9 months ago
Why water? Can't NaOH be used to substitute the azo group?
paopaomanalansan 9 months ago
awesome video! Is there a safe way (explosion hazard?) to make phenol from salicylic acid? I've heard that phenol is formed when salicylic is heated to about 200C. Is this method safe and/or feasible? i doubt you'd get a pure product if any.
spotlightman1234 9 months ago