really nice vid. if anybody's looking for a really nice overview of galvanic cells, i stumbled across a video on some guy's channel called J Co Review... it's short, sweet, and taught me in 5 mins what my prof failed to teach me in 45 lol
when mixing elements together, the more active element will go from an element to an ion. viceversa for the less active element. zinc is more active than copper therefore it wants to become an ion, the only way to become an ion is going into liquid. copper is the opposite....thought yaw all should know
My Chemistry book says that there won't be any current without the salt bridge, but from this video I understood it as that the salt bridge is needed if you want electrons to flow from the positive side to the negative side for a longer time?
@ThePharaoh9993 No it isn´t, an element for be considered a transition metal need to have its D orbitals uncompleted it´s because of this that these acquire its propierties that made them to call them "transition", Zn an Sc are in the block D thats right, but both element have complete D orbitals, so these dont present these properties so are not considered as transition metal, if you look the definition of a transition metal you will found that it is an element that has its D orbitals uncomplet
I've watched all the previous videos and have to say this one confused me quite a bit. Could you do a more in depth video explaining the "why's" there seems to be so much assumptions made without any basis.
The only thing I don't understand about Galvanic Cells is: Why the Zn is the one who Oxidates and the Ca is the one who reduces? Nobody never says that. If you know why, please answer.
When Sal says 1st year does he mean first year high school ie grade 9? :/ Im in the 12th grade and Im encountering this for the first time. Am I so far behind? D:
Thank you so much for making this video!!!! (And all your other ones) They REALLY help a LOT. I was staring at my book for a good hour on the galvanic cell section and NOTHING that I read registered in my head. But thanks to you, within 15 minutes, I have a much better understanding of galvanic cells! You're the BEST! <3
Thank you so much for making this video!! It helps me so much getting to SEE chemicals in action instead of just reading it in a book and wondering why elements keep changing place! We are learning about batteries in class now and I was struggling with redox reactions, this helped a lot. Thanks again =)
Hi. I have a question. What happens if u increase the concentration in the cells. if u put Cu(s) in CuSO4(aq). The koncentration gows down... If u instead put Zn(s) in ZnSO4(aq), it increases, with a few V... WHY??! What is it that happens...?.. Please help me with this.. Its a big assignment in my school, but i cant figure it out myself..:S...???
@AmirTunes because Copper is more noble ten Zinc. The non-noble metal is always getting oxidiced (Zn --> Zn+² + 2e-) and the noble one wants to get reduced into his elemental state (Cu+² --> Cu + 2e-).
@AmirTunes b/c on the activity series table, zinc is more higher on the table than copper, which means its more easily oxidized (go from Zn to Zn2+), if it were the other way around and copper was the solid, I don't think the reaction would take place bu im not sure...
@AmirTunes Being a spontaneous reaction, Cu^2+ is a stronger oxidizing agent. If you have a table, you'll notice Cu^2+ is higher than Zn(s) and on opposite sides.
@AmirTunes Well, this reply is really late, but for anyone who is wondering...It occurs spontaneously due to a potential energy difference. The potential energy of electrons is higher in the anode than in the cathode, so electrons flow spontaneously from the anode to the cathode.
Hello, so you say that the copper in the aq solution wants to go back to a solid, and the Zn solid wants to become an aq ion... why do they want to do this? Thanks!
anode is the +vely charged pole while the cathode is the -vely charged pole.anions are the particles which are attracted towards anode because they are -vely charged while cations are the particles which move towards the cathode because they are +vely charged.
I learned this in grade 12, and learned even more advanced concepts dealing with electro chemistry... But hey what can you do, this is but one reason why CANADA PWNS ALL!!!
Your current is flowing in the same direction as electron I think in your physics video on current you kept stressing that current flows in opposite direction.
tiny errors. but i still enjoyed the entire video. keep it up!
at around 5:30, you left the 2+ charge off the Zn on the right side of the half reaction.
at around 12:30, you said that a current was flowing but you drew an arrow going to the right. maybe you should have said that its the electrons that are flowing to the right since current flows to the left in your galvanic cell.
You are correct. Even though the electrons flow from the anode to the cathode, the convention is to say that "current" is flowing from the cathode to the anode. Maybe I'll make another short video to clear this up.
My essay is going to be a peace of cake, thanks to you!
salut295 1 day ago
really nice vid. if anybody's looking for a really nice overview of galvanic cells, i stumbled across a video on some guy's channel called J Co Review... it's short, sweet, and taught me in 5 mins what my prof failed to teach me in 45 lol
NeoWizard212 1 week ago
@10:42, shouldnt the zinc in the solution be Zn 2+,as in the ion, not Zn +2 the oxidation state?
mobinf 2 weeks ago
@khanacademy sholdnt the hlaf reaction be Zn--> (Zn^ 2+) + 2e-
Joeylumadip 3 weeks ago
@Joeylumadip yeah that must have been a typo...
SharathCK 1 day ago
CLARITY!
mrslovvet 1 month ago
cool video it makes sense now
wcastillo2501 1 month ago
Shouldn't the TotalE = .34 + .7 = 1.04 V ? Instead of 1.1V?
GenericCoder 1 month ago
@GenericCoder It was 0.76 see 7:50
MaxPaget 1 month ago
@MaxPaget I see I somehow heard him saying .7 instead of .76 V my mind must have been lagging :D.
Thanks.
GenericCoder 1 month ago
Comment removed
GenericCoder 1 month ago
@GenericCoder he said .34 + .76
Joeylumadip 3 weeks ago
This has been flagged as spam show
@Joeylumadip I see I somehow heard him saying .7 instead of .76 V my mind must have been lagging :D.
Thanks.
GenericCoder 3 weeks ago
when mixing elements together, the more active element will go from an element to an ion. viceversa for the less active element. zinc is more active than copper therefore it wants to become an ion, the only way to become an ion is going into liquid. copper is the opposite....thought yaw all should know
wowowwiwa 1 month ago
Great.
s0m0c 1 month ago
My Chemistry book says that there won't be any current without the salt bridge, but from this video I understood it as that the salt bridge is needed if you want electrons to flow from the positive side to the negative side for a longer time?
DENlERU 2 months ago in playlist Chemistry
Is a cathode positive or negative?
I think cathode is negative because It attracts cations, which are positively charged.
harshgupta11dec 2 months ago
This will help with my final tomorrow. Thanks!
juanpablodt 2 months ago in playlist More videos from khanacademy
At about 9:25 i think , what can that aqueous solution be , if you can give me a reaction on whats happening to each bar
999anonymosym 2 months ago
I thougth the cathode was negative in galvanic cells!!!!!!!
rafax8 3 months ago
This is excellent thank you!
andyroo2540 3 months ago
10:14 Sal Zn is not a transiction metal, but it´s just a tiny error dont worry, it doesnt affect the class :)
Villacis80 3 months ago
@Villacis80 Zn is a transition metal.
ThePharaoh9993 3 months ago
@ThePharaoh9993 No it isn´t, an element for be considered a transition metal need to have its D orbitals uncompleted it´s because of this that these acquire its propierties that made them to call them "transition", Zn an Sc are in the block D thats right, but both element have complete D orbitals, so these dont present these properties so are not considered as transition metal, if you look the definition of a transition metal you will found that it is an element that has its D orbitals uncomplet
Villacis80 3 months ago
@Villacis80 Actually it is. Just because it only has one charge doesn't mean it isn't a transition metal.
deadlyXviet 2 months ago
@AmirTunes nd @povern7 its bcz the E value of Cu is less positive than Zn thus making it easier to reduce hope it helps :)
cnfused100 4 months ago
That was a very good video, but I would suggest going more over spontaneous reactions, as in the Zn redox. reaction
GreatVgnc 4 months ago
I've watched all the previous videos and have to say this one confused me quite a bit. Could you do a more in depth video explaining the "why's" there seems to be so much assumptions made without any basis.
broli123 4 months ago
The only thing I don't understand about Galvanic Cells is: Why the Zn is the one who Oxidates and the Ca is the one who reduces? Nobody never says that. If you know why, please answer.
Like @AmirTunes asked, I want to know to. Why?
poveron7 4 months ago
Comment removed
EurekaTutoring 4 months ago
Salman has always been one of the best tutors on youtube. In fact, to some people words khanacademy and youtube became almost interchangeable:)
EurekaTutoring 4 months ago
Is it possible you can do a video on cyclic voltammetry, because I am really struggling with that.
205049770 5 months ago
So how can you tell which one is the anode and cathode?
Do electrons flow from the anode to cathode?
zacmiley12 5 months ago
Great vid!
topilopi123 5 months ago
redcat anox
BarcaB0y10 5 months ago
@thekobe157 those values are the set standard reduction potential values - they'll be in a table in your book
cr7sl7 6 months ago
Missing a salt bridge
shadows1313 6 months ago
is there's anyone here knows how he got the .34V and the .76V ?.
thekobe157 7 months ago
good video though,but how did you get the .34v in half reaction?,and .76v in the other reaction?.
thekobe157 7 months ago
When Sal says 1st year does he mean first year high school ie grade 9? :/ Im in the 12th grade and Im encountering this for the first time. Am I so far behind? D:
paelnaz001 8 months ago
@paelnaz001 No he meant 1st year of school as in kindergarten, are you really that far behind???
matthewscottgray 8 months ago
@matthewscottgray That was an honest serious question. Don't be such a dick.
paelnaz001 8 months ago
@paelnaz001
He means 1st year of chemistry, or the first chemistry class you take. Usually people learn this before 12th grade.
anonymous345 5 months ago
Thank you so much for making this video!!!! (And all your other ones) They REALLY help a LOT. I was staring at my book for a good hour on the galvanic cell section and NOTHING that I read registered in my head. But thanks to you, within 15 minutes, I have a much better understanding of galvanic cells! You're the BEST! <3
bunnie304 8 months ago
there should be more videos for electrocheistry. these vids are great, but the videos arent organised in a specific order,
AnotherBrownKid 8 months ago
I think he sounds like mike portnoy :O thanks for the video man :D <33
MrLaanix 9 months ago
thanks Jesus =]
bitememwah 9 months ago
love all your videos! wish u r my professor!!! =)
xinrui9181 9 months ago
Thank you so much for making this video!! It helps me so much getting to SEE chemicals in action instead of just reading it in a book and wondering why elements keep changing place! We are learning about batteries in class now and I was struggling with redox reactions, this helped a lot. Thanks again =)
jmama57 10 months ago
Comment removed
biostudent101 10 months ago
Hi. I have a question. What happens if u increase the concentration in the cells. if u put Cu(s) in CuSO4(aq). The koncentration gows down... If u instead put Zn(s) in ZnSO4(aq), it increases, with a few V... WHY??! What is it that happens...?.. Please help me with this.. Its a big assignment in my school, but i cant figure it out myself..:S...???
TheNothingsomething 10 months ago
what about reduction potential?can u make some video about this?
yayaagogo 11 months ago
17:38 You meant K+ (Potassium), not Na+ (Sodium).
Na+ will jump into the solution with the Copper bar to replace the Copper jumping out.
riyarsr 11 months ago
OWWW!!!!! that hurt! Why did you have to copy and past the reaction down there!! Oww..
66CrtS 11 months ago
great :) im german but your way of explaining is that good that its easier for me to watch your version in english than the teacher's in german
B3rNd92 1 year ago
actually, i hav prob in electrolytic cell. so, can anyone plz tel 2 me whr is best website 4 tat topic? urgent, coz i;m havin exam in 2days. thank u.
missfun24 1 year ago
I've never understood the concept of salt bridges until now. You're amazing!!!
dawance88 1 year ago
How come the Zn wants to jump off of the bar, but the Cu wants to jump onto the bar?
AmirTunes 1 year ago 11
@AmirTunes because Copper is more noble ten Zinc. The non-noble metal is always getting oxidiced (Zn --> Zn+² + 2e-) and the noble one wants to get reduced into his elemental state (Cu+² --> Cu + 2e-).
i hope that helped..
ELLo1997 7 months ago
@ELLo1997 Thanks! :) It's just that my chemistry class ended about 6 months ago, but still thanks. :)
AmirTunes 7 months ago
@AmirTunes oh ok ^^
ELLo1997 7 months ago
@AmirTunes b/c on the activity series table, zinc is more higher on the table than copper, which means its more easily oxidized (go from Zn to Zn2+), if it were the other way around and copper was the solid, I don't think the reaction would take place bu im not sure...
hellokittydimaggio 3 months ago
@AmirTunes Its because electronegativity which is the measure of how much atom want to attract electron.
The Zinc electron would tend to jump to the Cu.
GenericCoder 1 month ago
@AmirTunes Being a spontaneous reaction, Cu^2+ is a stronger oxidizing agent. If you have a table, you'll notice Cu^2+ is higher than Zn(s) and on opposite sides.
TheAbsoluTurk 1 month ago
@AmirTunes Well, this reply is really late, but for anyone who is wondering...It occurs spontaneously due to a potential energy difference. The potential energy of electrons is higher in the anode than in the cathode, so electrons flow spontaneously from the anode to the cathode.
KoreaxxLove 1 week ago 2
Hello, so you say that the copper in the aq solution wants to go back to a solid, and the Zn solid wants to become an aq ion... why do they want to do this? Thanks!
AmirTunes 1 year ago
anode is the +vely charged pole while the cathode is the -vely charged pole.anions are the particles which are attracted towards anode because they are -vely charged while cations are the particles which move towards the cathode because they are +vely charged.
tom2king 1 year ago
im having so much trouble in my ap chem class but this clears it up ALOT!! :] thank you!!
k00lieo417 1 year ago
isnt it supposed to be a salt bridge too? or am i wrong
lnvfednk 1 year ago
browsing YOU TUBE for last 5 hours , finally you are the only one who explained from elementary level.. thank you
propnash 1 year ago
thats great, i was wondering, have you done electrolysis?
irmb5teS 1 year ago
thanks sal. one of your best
MJsDisciple 1 year ago
thank you for the help :)
atong518 1 year ago
Thankyou SO much.
This is amazing.
amm23ka 1 year ago
Lol, this video is just fucking amazing. You wouldve thought that God made it.
SteroidsR4success 2 years ago
@SteroidsR4success God doesn't talk so much)
GingleGangle1 1 year ago
You should actually contrast Oxidation/Reduction and
Cathode/Anode charges of Galvanic Cell to an Electrolytic cell in which the anode is (+) and Cathode is (-)
drstingrae 2 years ago
where did you do your studies?
high school, university, etc
must be real good schools cause your teaching is so good!
NJKjonasfan4ever 2 years ago
This is ridiculously helpful i have an exam tomorrow ans had to know this concept
JacobLJacques 2 years ago
Wow... The US is very behind.
I learned this in grade 12, and learned even more advanced concepts dealing with electro chemistry... But hey what can you do, this is but one reason why CANADA PWNS ALL!!!
proffezur 2 years ago
@proffezur Dude, get off your pedestal. I'm in the US, I'm in grade 12, and I'm learning this material.
LegoCritic 1 year ago
@LegoCritic Wow Really? Oh I remember when I learned this stuff... Way back in grade 12. >_>
proffezur 1 year ago
@proffezur im learning this right now and im in 10th grade :)
XyellojelloX 1 year ago
very useful!thx!
there's also a mnemonic trick to remember the odiation...you say it' the A&O (alpha and omega)
so on the anode theres the oxidation (A&O)
greetz
Vali1012 2 years ago
Preparing for the SAT chem, and the books explain this very poorly. Thanks for the thorough yet easy-to-understand tutorial.
desoan 2 years ago
At the begining, you call Cu 2+ (aq) "molecules", but they're just atoms.
cow2001 2 years ago
No they're not ;) Cu 2+ are "ions". He calls them molecules because these ions are bonded to another molecule like SO4 2- which makes up a molecule.
Blueknightex 2 years ago
A molecule is a bunch of atoms joined together by covalent bonds. Between copper and sulfate there's an ionic bond, not covalent.
cow2001 2 years ago
By the way an ionic bond is between a metal and a non-metal.(two 'single' elements).
SO4 2- is not a non- metal it is a "molecule"(made up of elements sulfur and oxygen).
So when Cu 2+ is bonded to it they form a "molecule".
Blueknightex 2 years ago
They re ions, not atoms
iGustaf 2 years ago
Your current is flowing in the same direction as electron I think in your physics video on current you kept stressing that current flows in opposite direction.
vkgoku2012 2 years ago
When are you gonna cover E knot.
vkgoku2012 2 years ago
tiny errors. but i still enjoyed the entire video. keep it up!
at around 5:30, you left the 2+ charge off the Zn on the right side of the half reaction.
at around 12:30, you said that a current was flowing but you drew an arrow going to the right. maybe you should have said that its the electrons that are flowing to the right since current flows to the left in your galvanic cell.
gamefaq 2 years ago 9
You are correct. Even though the electrons flow from the anode to the cathode, the convention is to say that "current" is flowing from the cathode to the anode. Maybe I'll make another short video to clear this up.
khanacademy 2 years ago 5