I understand the theory behind hexanediamine and decandiachloride and that it reacts in the boundary between Water and Hexan - but why does it have to be aquious Sodiumhydroxide and not just water?
da entsteht HCl bei der amidbildung. R-NH2 + Cl-CO-R' gibt R-NH-CO-R' +HCl
das fängst du mit NaOH ab zu wasser und kochsalz. außerdem erhöhst du die nucleophilie des amids vielleicht noch nen bisschen, wenn du es gleich deprotonierst und das dadurch schneller ans säurechlorid addieren kann.
hexan ist da gar nicht drin so wie ich das verstande habe.
@paopaomanalansan No, not at all. It just indicated with a photo that this was feasible. But now with Polymer Chemistry courses taken, I can confirm that it was impossible. Interphase polymerization can only occur with acid chloride. :-)
yes they are silly me a grade 10 student mixed these diminohexane and sebacoyl chloride together as two raw chemicals .. supposedly the fumes that were produced could of seriously injured someone - thank gosh we did it in the fume cabinet.
would you know a safe precedure to make this synthesis by subsituting sebacoyl chloride for adipoyl chloride and doing the same procedure to form nylon 6,6 ?
hah....
d'scul cma da bacot tpi liat d'you tube tak palah
Luthfi894 3 months ago
cool ...my teacher always talks about this experiment...but this is the first time I see it...It's coolest than my teacher talking.
BeeDootube 4 months ago
looks like snott
animal560 1 year ago 2
Yeah, now I can make my own plastic bags for groceries!
IndiePharm 1 year ago 9
we did this in our final lab for organic chemistry.....by far my favorite chem lab ever done :)
grndmstrjoe 1 year ago
Actually it is really a shame that I know the reaction. Because this would else look like true magic.
jeroen2006 2 years ago
It is called an interfacial polycondensation reaction.
douro20 2 years ago
anyway i prefer cotton ;]
DBGokussj3 2 years ago
I understand the theory behind hexanediamine and decandiachloride and that it reacts in the boundary between Water and Hexan - but why does it have to be aquious Sodiumhydroxide and not just water?
Alkoholtest 2 years ago
da entsteht HCl bei der amidbildung. R-NH2 + Cl-CO-R' gibt R-NH-CO-R' +HCl
das fängst du mit NaOH ab zu wasser und kochsalz. außerdem erhöhst du die nucleophilie des amids vielleicht noch nen bisschen, wenn du es gleich deprotonierst und das dadurch schneller ans säurechlorid addieren kann.
hexan ist da gar nicht drin so wie ich das verstande habe.
haubsen 2 years ago
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pengie32 3 years ago
I can't purchase ClCO(CH2)4COCl. Did you prepair this by yourself?
Some book said that HOOC(CH2)4COOH can also be used in this experiment. I did as it said, but no reaction at all.
PeterCarneades 3 years ago
@PeterCarneades the acid chloride is more reactive than carboxylic acid...maybe the book instructed to use some catalyst..??
paopaomanalansan 1 year ago
@paopaomanalansan No, not at all. It just indicated with a photo that this was feasible. But now with Polymer Chemistry courses taken, I can confirm that it was impossible. Interphase polymerization can only occur with acid chloride. :-)
PeterCarneades 1 year ago
@PeterCarneades Is an anhydride reactive enough for acylation reactions?
paopaomanalansan 1 year ago
I did this in the first year of my study. It's a quite cool experiment! Indeed you should handle the chemicals with care..
Savatage0087 3 years ago
That sabacoyl chloride, always up to some shananagin.
Abercr0mbie4life 3 years ago
what a boring job to talk about that crap! LOL
bmcm10 3 years ago
@bmcm10 I can see how it must seem boring to you? All those big words they use, and you having to pause every few seconds to look them up.
kawana87 1 year ago
it's amaizing.....could u send me the video it could come in handy... i needed for a work of chemistry.... thanks for your attencion
cisar18 4 years ago
amazing
robglobetrotter 4 years ago
Actually, according to Wikipedia, those two chemicals are quite toxic.
denelson83 4 years ago
yes they are silly me a grade 10 student mixed these diminohexane and sebacoyl chloride together as two raw chemicals .. supposedly the fumes that were produced could of seriously injured someone - thank gosh we did it in the fume cabinet.
sakuranohana1523 3 years ago
Very cool and this is a synthetic organic chemist watching!
c0kement0s 4 years ago
would you know a safe precedure to make this synthesis by subsituting sebacoyl chloride for adipoyl chloride and doing the same procedure to form nylon 6,6 ?
sakuranohana1523 3 years ago
Amazing....are these two chemicals available from most suppliers and reasonably safe to use. i`m talking about suitablity for a school demo
craynerd 4 years ago
awesome
4524352353 5 years ago
wow
iv81 5 years ago
hehe, cool
hypergoth 5 years ago